Hello Ian.
Part of working life has been spent working in the gas industry involved with issues of Gas Safety.
The Gas safety Installation and Use regulations in conjunction with the LPGA safe working practices require that all vapour phase take-off LPG bottles must remain upright and secured at all times. This includes transport, storage and use.
It is potentially very dangerous to lay LPG vapour phase bottle on their sides It is illegal so DON'T DO IT.
LPG bottles contains butane (or propane) under pressure in two phases: liquid and vapour. When Butane or Propane is compressed enough the gas vapour will turn into liquid. The liquid, being heavier than the vapour, collects at the bottom of the bottle and some vapour remains above it. In a vapour take off bottle, the valve neck is situated at the top of the bottle to ensure it only admits gas vapour. To ensure the bottle has an adequate vapour take off capcity, the neck of the valve is relatively large.
If the bottle is not in its vertical position, it is highly likely that the neck of the valve will be immersed in the liquefied gas rather than the vapour. If the valve were to be opened, then it would admit liquefied gas, which has a much greater energy content than the same volume of vapour. (approx 230:1)
As the liquid emerges the lower external pressure will cause the liquid to try to expand. It does this by adsorbing heat energy from and cooling its immediate surroundings. Skin would suffer significant ice burns if it came into contact with it.
If sufficient air is available it will rapidly form a highly explosive mixture, which if ignited will have quite devastating blast, but also turn the gas bottle into a liquid fuelled rocket. Sadly it is not aerodynamically designed thus its path is not predictable. Incidentally if a bottle correctly secured in the upright position were to suffer valve damage only the vapour will emerge. If ignited it too has an explosive effect, but the rocket effect is substantially reduced and because the bottle is secured it will only try to push the bottle into the ground.
Contrary to popular belief the bottle its self is unlikely to explode, but if it did you have a lot of steel shrapnel to dodge.
LPG bottles for caravans and other domestic uses are of the type above. Bottles used for forklift trucks and other motive power systems are usually designed for liquid take off. Here the neck of the valve is designed to be below the level of the liquid. It has a smaller orifice, and so it I less able to discharge large quantities of liquid at a rate to provide rocket propulsion, and the bottle is usually restrained on a heavy vehicle.
Graham, If a transport company moves Vapour Phase Bottles on their side they are breaking the law, and endangering the public and staff. That is an offence under HSE legislation.
Alan and Lisa LPG sadly a history of not having any incidents when carrying LPG bottles on their side is not an indication of a safe practice. It only demonstrates that you have been lucky. You may also be surprised that even though you are not using the gas for work, you are still obliged to conform to the safe working practices as recognised by the HSE. In the event of an incident where your bottle was in close proximity to or the cause of the incident you may be prosecuted.
When the HSE bring a prosecution under safety related legislation it is viewed as very serious and as such it is brought under criminal law rather than civil law. Equally the sanctions that can be imposed include fines and prison. As ever, ignorance is no defence.