saint-spoon said:
as an engineer I am intrigued as to how the gauge is supposed to work.
Whilst there is still liquefied gas in the cylinder the pressure is dependent on the temperature of the cylinder contents (and type of gas), the pressure will only start to drop once all of the liquid gas has evaporated.
Hello SS,
Yes that is the obvious conclusion, but there is a bit more to t that that:-
The type of the gas in your cylinder is not perfectly pure butane or propane, this is because the commercial fractionisation of crude oil is not precise. The gas will have some other fractions mixed in with it, sometimes added deliberately to bring its calorific values into the correct commercial range. Each different fraction will have its own pressure and temperature characteristics, and boil off temperatures. Generally speaking the lower the boil off temperature, the high its vapour pressure for any given temperature.
Consequently when you have a fresh cylinder it will have all the fractions its supplied with. As you start to use it, those fractions with a lower boiling point will tend to boil of and be used up first, But as the liquid is bubbling (boiling) it is mixing, so the proportions of the fractions in the vapour change slowly. As the cylinder is progressively used, you will be left with a greater proportion of lpg's with higher boiling points and thus slightly lower vapour pressures. Consequently over the life of a cylinder, you may see a reduction in the vapour pressure for the same temperature. Generally this change is relatively small, and as you correctly point out the biggest pressure drop will occur when all the liquefied gas has been evaporated, and you are literally running on fumes.
We must not also forget the temporary self cooling effect of the cylinder when the latent heat of vaporisation cools the remaining liquid in the cylinder, which drops the cylinders temperature, and in extreme cases causes frosting on the outside. The pressure will rise as the cylinder is able to take up heat from the atmosphere around it.
This effect is more obvious with butane than propane as propane naturally has a lower boiling point adn teh other gasses involved generally have higher BP's