Colin makes a very good point about jump leads. But even jump leads can heat up when the flat battery is connected to a fully charged battery. How much they heat up depends on the length, and resistance of the jump leads, and the current that flows when they are connected. Certainly with cheaper jump sets, its often the spring clips that suffer the most because they cant make enough contact area with the battery terminals.
So if a parallel connection is to be made, ensure you have good quality terminal connectors that have a large contact area. Use a cable with a large cross-sectional area, - an old jump set could be a good donor for the cable.
There are several different types of battery for example Leisure, Traction, Starter and whilst they may look similar on the outside, they will have a different internal construction to suit the usage they are designed for.
All types of battery will wear out, and its condition will affect its ability to accept charge and to deliver current. If you mix types or conditions of battery in a parallel configuration, you can get some substantial currents flowing between the two batteries. It this situation that you should avoid.
To avoid problems of transfer currents ideally always use two new batteries of the same make, type and size as this ensures both batteries will be in the same condition. Problems can arise if the two batteries are not in the same condition, type or size.
But in conclusion, I like others have to ask why the OP needs so much more battery capacity with the issues its brings of weight and stowage etc.