Hello Oldfogey,
What you are suggesting will work but you must take some additional precautions;
Ideally contain the battery is a closed box, which has a vent pipe from the top to the outside. This is to allow the hydrogen gas that can be given off a chance to escape and not build up to present an explosion or fire hazard.
The connection cables should be fully insulated even over the battery clips, to minimise the possibility of accidentally shorting the battery or the car electrics. For added protection both the + & - wires should have 10 or 16A fuses in circuit, again to protect from faults of accidental short circuits.
The battery, and the box must be secured so that it does not move when cornering or breaking.
I use a similar system, but I make up a cable set into a 12S plug so that is only plugged in when I intend to charge the battery. This means there is no additional car wiring, other than the normal tow sockets.
Check that the boot seal is sufficiently compliant to allow both the 12V cable and the vent pipe to be held in place without damage when the boot/tailgate is closed.