Hi Steven.
I have towed trailers both single and twin axle for 33 years.
You are quite right to say that your tow tug is capable for both vans.
Twin axle vans are more stable by virtue of the fact that you have four wheels aligned to flow in a straight line. Where as, a single axle van does tend to pivot (sway) a little easier as it pivots more freely at the tow ball. However a single axle van correctly loaded and I would suggest loaded to a minimum of 75Kgs nose weight should tow fine.
As already mentioned, you will need to be accurate at backing up to the hitch as usually you only have about an inch or so of persuassion available sideways to hook up.
One thing you will notice more on a twin axle van is the tendancey to pitch up and down over a bumpy road. This is due to the fact that you have independantly sprung axles, which means that the nose weight increases/decreases as you traverse a speed bump for instance.
One last area where a single might suffer worse is in a cross wind, and especially one where you have 10ft of overhang behind the axle. You might need to adjust your road speed downwards a little on a windy day and just be a bit more alert of your surrounding building/hill profiles, also going over via ducts and passing lorries and coaches.
You will also find a single axle van easier to move by hand. Also with a twin axle it is more prefferable that you are able to reverse proficiently. Which is not to say that any person who tows shouldn't be able to reverse their outfit, after all one needs to be capable of towing in any direction.
Over all though a single axle van is just as livable in as a twin axle, so I would say it is more down to personal choice.
Regards.
Steve L.