It is an interesting question, use as pair, or use in sequence? On narrow boats they tend to have a battery engine only, and rest all in parallel idea is the less percentage discharge then to quicker to recharge, however not quite that easy.
If the solar panel has fully recharged the battery by night fall, then it is likely a second battery could absorb more charge, however if it has not fully charged one battery, then there will no be any spare power to charge a second.
Unlike the canal boat where engine runs for maybe 6 hours, a solar panel charges for 8 to 16 hours depending on time of year, so in the main it has time to recharge the battery, and time is the key.
Alternating batteries one being used and charged the other one being charged only will likely ensure batteries get fully charged when being charged with an alternator able to deliver 70 amp. However with solar panels we are likely using more than that can deliver anyway so alternating batteries or even doubling up on batteries is unlikely to help.
There are some items that must use electric, water pump can be foot operated but in real terms has to be electric, gas lights have gone, has to be electric, but it can use LED to reduce demand, but cooking has to be gas, and items like Tv's have to be resistricted to a few hours a day.