hi all.
sorry John, logic is all I have to work with not being a professor or anything, that and experiment or course
.
2 points, first so resistance doesn't cause heat eh! erm, I thought it was something to do with thermal dynamics and all that, you know the one, the bit about how a light bulb and elecric fire works, the senario you propose is of course correct if the zig unit is of the smart charger type and reduces the current as the resistance in the state of battery charge becomes higher, trouble is zig units are not smart chargers,
second, experiment we all have some sort of charger at home, place on flat suface connect a battery and plug into the mains, leave for 1hour, turn off then check the temprature of the charger, next do the same thing but this time place the charger in a box fit lid and cover with insulation, run again for an hour,(if the charger lasts that long without blowing a fuse) check the temp again it will be considerably warmer due to the lack of air circulation.
I do agree however that the main reason the charger would heatup considerably would be due to a duff battery and not electrolisis alone, but it doesn't help.