Last winter my workshop butane gas cylinder would run for a few seconds and cut out . Sub zero temps causing “icing “. Must get round to changing it to Propane👍.The issue only happened when the cylinder was less than a quarter full. Not sure I know what “gassing off” means? A local dialect?
"Gassing off" is actually how LPG cylinders work. Liquified Petroleum Gas (LPG) in side the cylinder has to boil (Gass Off) to produce the gas vapour we use.
If the liquified gas is not warm enough it wont boil - its the exactly the same process as boiling water, if its not warm enough it won't boil to produce steam (which is a gas)
Liquified Butane need to be above about -1C to boil at normal atmospheric pressure, but in a cylinder its held under pressure to realistically it needs to be about about 2C or more to boild and produce butane gas.
One of the problems is , the heat energy need to phase change the Butane has to come from the mass of the liquified gas, so as the energy is used it actually cools the liquified gas, and if it cools it too much, the remaining liquified gas won't be warm enough to vapourise any more gas.
The liquified gas will normally pull heat in through the walls of the cylinder. if the ambient temperature is too low, there won't be enough heat transfer to vaporise the gas.
A full bottle of gas has a greater surface area in contact with the liquified gas, so it will manage to collect more ambient heat energy to keep the liquified gas boiling than a part used cylinder using gas at the same rate
Most users are not necessarily familiar with the technicalities of how LPG cylinders actually work, so they often incorrectly describe a butane cylinder as freezing, when in fact the the gas hasn't frozen (ie turned to a solid) its still liquified, but its simply not warm enough teo allow it to boil and "gass off"