Hello Alan,
I am of the view that the wheels should be chocked and the hand brake should be off.
My reason for adopting this view is; that caravan must be free to rotate on its axle. If it is restricted through the action of the brakes, it will affect the force created at the tow hitch.
The effect may either increase of decrease the apparent nose load, depending on which way the caravan was moving when the brakes were applied.
In reality the effect may not very large, but it could make the difference between being legal of not.
It is only fair to point out that there are other factors that will also affect the nose load, so it is important to keep things as consistent and repeatable as possible.
The caravan must be on level ground, the tow hitch must be at the same height as when it is attached to the car and the load must be transferred through a vertical pole.