Hello Ian.
Technically Butane has a higher calorific value than Propane, thus to achieve the same heat input through the same injector and burner means that propane has to be supplied at a higher pressure than butane. Hence the older UK settings of 37mB Propane and 28mB for Butane. Consequently if you supply a butane burner with propane gas at the lower pressure of butane, you will have a lower heat input into the appliance.
That is not the whole story, because to archive proper combustion, the pure gas has to mix with entrained air in the venturi tube inside the burner. The propane injected at a lower pressure may not have the velocity and thus momentum to entrain enough air for complete combustion, resulting in high levels of the poisonous gas Carbon Monoxide.
In some appliances where the system employs a pilot flame, the lower heat input rate may affect the size of the flame and its stability. Where the appliance has a user controlled regulator valves (e,g, a cooker) where there is a minimum detent, the flame on propane may be too small and thus prone to blowing out.
I cannot quote regulation numbers as I don't have a copy due to being retired from the industry, but having worked for many years with an LPG Gas appliance manufacturer, I am conversant with the way the regulations are applied.
The appliance manufacturer must apply for CE approval before a new gas product can be sold in the UK. The CE approval for gas appliances unlike CE for many other items cannot be self certified, it has to be tested and ratified by an independent Namas approved test house.
Part of that process involves checking the safety of combustion on the range of gasses and pressures stipulated by the manufacture and any relevant construction regulations of which there are many.
Most manufactures would try to make an LPG fuelled appliance compliant on both Butane and Propane, but some devices may not provide safe combustion on both gasses.
Under these circumstances the appliance will only be CE approved for use on one type of gas with a specified pressure regime.
The Gas (Installation and Use) regulations, govern the application to which any gas appliance can be used. They require that the appliance must be CE approved and may only be installed and used in accordance with the manufactures installation instructions and the Accepted Codes of Practice. (ACOPS) for gas installations. Installations, service and removal must be carried out by a competent person. A person connecting a butane only appliance to a propane supply would be deemed incompetent, and that would be a breach of the regulations.
Health and safety regulations identify that the person responsible for any gas appliance must ensure it is in a safe condition. Using Propane on an appliance only approved for butane would be deemed as unsafe, and thus in breach of the H&S regs. Prosecutions under H&S regs are conducted under criminal law.