I have to agree with Martin, solar charging can be very effective, and can eliminate the need for a second battery, which also reduces the weight you have to carry.
I cant support Woody's method in the context of the OP's question:- A used older battery will have lost some of its ability to be charged to its full stated capacity. This is usually shown by the batteries unloaded terminal voltage, which will be lower than a fully charged new battery. If you connect these two batteries together in parallel, the higher voltage battery will try to discharge to the lower battery. as these battereies are lead acid accululators, they can produce some very high currents, which can certainly heat up even thick cables and possibiliy damage either the cable or the batteries. At worst it coudl be possible that the combination of chemical reactionand teh heating effect of a current through a conduictor coudl cause one or both batteries to explode.
That is why when ever paralell battery systems need one battery replacing, it is recommended practice by most manufactures to replace both batteries at the same time.