Hi Ron,
Silicone sealant releases acids during the curing process that can attack aluminium - so it's not a great idea to use it on an aluminium clad caravan.
Sikaflex (Sika Ltd) is a constructional mastic, often used to bond car windscreens to the car, and is available in a range of "stickness" - so if you want to get the awning rail off again, then choose a low strength (also means more flexible) Sikaflex
Alternatively a Butyl Mastic (Hodgson Sealants) is often the best product for awning rails and windows - this will stay flexible for many, many years - but unlike the Sikaflex products, mastic has no "tack" or "grab" which you may regard as a good or bad thing
Try Google for the manufacturer web-sites and distributors.
Robert