Hello Clive,
Technically LPG always stands for liquefied Petrolum Gas. In reality it can be any petreum gas that can be liquified, by increasing pressure or cooling it.
Pure propane does exsist as a 'test gas'used by appliance manufactures to test an appliance for performance and compliance to the relevant standards. Similarly there are pure versions of most LPGs for the same reasons.
Commercial gasses such as those sold by Calor have to conform to some standards but are rarely pure. they usually contain varying proportins of other Hydrocaron gasses. This is either by design or through the coarser and thus cheaper frationising process that makes the gas.
The mixing of some Propane with butane is quite common to help with lower temperatures, but other Hydrocarbons will also be present.
As for the mix of comercial propane across Europe, there are international standards for particular grades of gas, but as with petrol there can be variations within that standard and between manufactures. Some national standards vary as well, so rather than a gradual change of the mix supplied across to Spain, it is more likely to change at boarders, and with the supplying company.
There are significant differences in the mix of natural gas supplied to homes, so much so that manufactures of appliances wishing to supply accross europe have to arrange for special supplies of test gassess to be able to test thier appliances. In fact some manufactures find they still have make small changes to appliances to make them work and therfore saleable for some EU countries.
To demonstrate how variable gas supplies can be: look inside your caravan refridgerator. You will probably find that it has a printed lable, and on it, it will list the countries and the relevant gas categories that apply.